To the best of my knowledge:

1. They represent 3 different things.
Energy is the sum of energy from all sources (fat, carbohydrate, and protein) in 100 grams.
Total fat means only the fat content per 100 grams.
Carbohydrate means only the carbohydrate content per 100 grams.

2. Carbohydrate is not the only source of energy. There are 3 sources of energy: fat, carbohydrate, and protein.

3. The total carbohydrate content of this whole package is 58.4 x 4 = 233.6 grams.
There are 40 individual packages in the big package.
233.6 / 40 = 5.84. So one small package has 5.84 grams of carbohydrate in it.
If you want 60 grams of carbohydrate, you have to eat 60 / 5.84 = 10.27 small packages.

4. The content stated is per 100 grams.
There should be the table of nutritional information in the back of the package. Look at it.

"แล้วเมื่อเปรียบเทียบ Total Fat  กับ คาร์โบไฮเดรต Total Fat ที่เขียนว่ามีปริมาณ 46% แต่ดันมีน้ำหนักน้อยกว่าคาร์โบไฮเดรตมีมีสัดส่วน 19%"
I don't think the energy yield (fat 9, carbs 4, protein 4) matters in this case. I tried to incorporate that into the explanation but I don't think it's relevant.

I'm not sure what they base that on but according to the United States FDA, the recommended percent daily value for:
Total fat: 65 grams
Total carbohydrate: 300 grams
http://www.fda.gov/Food/GuidanceRegulation/GuidanceDocumentsRegulatoryInformation/LabelingNutrition/ucm064928.htm

In other words, you need more carbohydrate than fat daily. And that's what you use to calculate your nutritional intake.

THEREFORE,
For the fat (27.6 x 100) / 46 = 60 grams ======> 27.6 is 46% of 60. So they base it on 60 grams.
For the carbohydrate (58.4 x 100) / 19 = 307.37 grams ======> 58.4 is 19% of 307.37. So they base it on 307 grams.

So, roughly, you need 60-65 grams of fat per day and 27.6 grams is about 46% of it;
and you need about 300 grams of carbohydrate per day and 58.4 grams is about 19% of it.

Are you following me?